Question

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Answer (Detailed Solution Below)

Option 3 : +146.7 kJ mol−1

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Detailed Solution

सही उत्तर +146.7 kJ mol−1 है।

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Question:

For the reduction Zn2+ + 2e− → Zn, E° = −0.76 V. The standard Gibbs free energy change, $\Delta G^\circ = -nFE^\circ$, is / अपचयन Zn2+ + 2e− → Zn हेतु E° = −0.76 V है। मानक गिब्ज़ मुक्त ऊर्जा परिवर्तन, $\Delta G^\circ = -nFE^\circ$, है

1.
−146.7 kJ mol−1
2.
−73.3 kJ mol−1
3.
+146.7 kJ mol−1
4.
+73.3 kJ mol−1

Correct Answer: +146.7 kJ mol−1

ΔG° = −nFE° = −2 × 96500 × (−0.76) = +146.7 kJ mol−1; the negative reduction potential makes the reduction non-spontaneous under standard conditions. / ΔG° = −nFE° = −2 × 96500 × (−0.76) = +146.7 kJ mol−1; ऋणात्मक अपचयन विभव मानक परिस्थितियों में अपचयन को अस्वतःप्रवर्तित बनाता है।

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